蒸汽重整反应器调研与分析

摘要/Abstract

摘要： 对国际上已有的废物蒸汽重整反应器形式,包括管式炉、固定床、流化床、喷射床、回转窑及螺杆反应器等进行了调研,比较分析了各种反应器的特点和局限性。在实际应用中,应根据具体的处理对象和工况,选择合适的蒸汽重整反应器形式。

Abstract: A literature review on existing forms of waste steam reforming reactor, including tube furnace, fixed bed, fluidized bed, spouted bed, rotary kiln, and screw reactor, is presented. Their characteristics and limitations are compared and analyzed. In practical applications, the appropriate form should be selected according to the specific treatment objects and working conditions.

Key words: Radioactive waste, Treatment, Steam reforming, Reactor

中图分类号:

TL941

张禹, 阮佳晟, 郑博文, 杨丽莉, 徐卫, 褚浩然. 蒸汽重整反应器调研与分析[J]. 辐射防护通讯, 2019, 39(4): 39-48.

Zhang Yu, Ruan Jiasheng, Zheng Bowen, Yang Lili, Xu wei, Chu Haoran. Investigation and Analysis of Steam Reforming Reactor Forms[J]. RADIATION PROTECTION BULLETIN, 2019, 39(4): 39-48.

参考文献

[1] 林力, 马兴均, 陈先林. 放射性废物蒸汽重整处理及矿化技术发展现状及展望[J]. 科技创新导报, 2015(18):6-10.
[2] 李斗, 华伟, 廖能斌. 蒸汽重整处理核电厂放射性废树脂的探讨[J]. 广州化工, 2015(15):157-158.
[3] Stevens H, Laurent G. Treatment of irradiated graphite from French Bugey reactor[C]//ASME 2013 15th International Conference on Environmental Remediation and Radioactive Waste Management. American Society of Mechanical Engineers Digital Collection, 2014.
[4] Song H J, Lee J, Gaur A, et al. Production of gaseous fuel from refuse plastic fuel via co-pyrolysis using low-quality coal and catalytic steam gasification[J]. Journal of Material Cycles & Waste Management, 2010,12(4):295-301.
[5] Yan F, Luo S, Hu Z, et al. Hydrogen-rich gas production by steam gasification of char from biomass fast pyrolysis in a fixed-bed reactor: Influence of temperature and steam on hydrogen yield and syngas composition[J]. Bioresource Technology, 2010,101(14):5633-5637.
[6] Czernik S, French R J. Production of hydrogen from plastics by pyrolysis and catalytic steam reform[J]. Energy & Fuels, 2006,20(2):754-758.
[7] Kantarelis E, Donaj P, Yang W, et al. Sustainable valorization of plastic wastes for energy with environmental safety via High-Temperature Pyrolysis (HTP) and High-Temperature Steam Gasification (HTSG)[J]. Journal of Hazardous Materials, 2009,167(1-3):675-684.
[8] Li J, Liao S, Dan W, et al. Experimental study on catalytic steam gasification of municipal solid waste for bioenergy production in a combined fixed bed reactor[J]. Biomass and Bioenergy, 2012,46:174-180.
[9] Luo S, Zhou Y, Yi C. Syngas production by catalytic steam gasification of municipal solid waste in fixed-bed reactor[J]. Energy, 2012,44(1):391-395.
[10] Zheng X, Chen C, Ying Z, et al. Experimental study on gasification performance of bamboo and PE from municipal solid waste in a bench-scale fixed bed reactor[J]. Energy Conversion and Management, 2016,117:393-399.
[11] De Sales C A V B, Maya D M Y, Lora E E S, et al. Experimental study on biomass (eucalyptus spp.) gasification in a two-stage downdraft reactor by using mixtures of air, saturated steam and oxygen as gasifying agents[J]. Energy Conversion and Management, 2017,145:314-323.
[12] Ponzio A, Kalisz S, Blasiak W. Effect of operating conditions on tar and gas composition in high temperature air/steam gasification (HTAG) of plastic containing waste[J]. Fuel Processing Technology, 2006,87(3):223-233.
[13] Namioka T, Saito A, Inoue Y, et al. Hydrogen-rich gas production from waste plastics by pyrolysis and low-temperature steam reforming over a ruthenium catalyst[J]. Applied Energy, 2011,88(6):2019-2026.
[14] Park Y, Namioka T, Sakamoto S, et al. Optimum operating conditions for a two-stage gasification process fueled by polypropylene by means of continuous reactor over ruthenium catalyst[J]. Fuel Processing Technology, 2010,91(8):951-957.
[15] Sun H, Rosenthal C, Schmidt L D. Oxidative pyrolysis of polystyrene into styrene monomers in an autothermal fixed-bed catalytic reactor[J]. ChemSusChem, 2012,5(10):1883-1887.
[16] Mason J B, Myers C A. THOR? Steam reforming technology for the treatment of ion exchange resins and more complex wastes such as fuel reprocessing wastes[C]//ASME 2010 13th International Conference on Environmental Remediation and Radioactive Waste Management. American Society of Mechanical Engineers Digital Collection, 2011:171-178.
[17] Mason J B, Bradbury D. Process for the treatment of radioactive graphite: U.S. Patent 6,625,248[P]. 2003-9-23.
[18] Mason J B, Bradbury D. Pyrolysis and its potential use in nuclear graphite disposal[R]. 2001.
[19] Mason J B, Oliver T W, Carson M P, et al. Studsvik processing facility: Pyrolysis/steam reforming technology for volume and weight reduction and stabilization of LLRW and mixed wastes[M]. American Institute of Chemical Engineers, 2000.
[20] Mason J B. Pyrolytic decomposition of organic wastes: U.S. Patent 6,084,147[P]. 2000-7-4.
[21] Erkiaga A, Lopez G, Barbarias I, et al. HDPE pyrolysis-steam reforming in a tandem spouted bed-fixed bed reactor for H2 production[J]. Journal of Analytical and Applied Pyrolysis, 2015,116:34-41.
[22] Erkiaga A, Lopez G, Amutio M, et al. Syngas from steam gasification of polyethylene in a conical spouted bed reactor[J]. Fuel, 2013,109:461-469.
[23] Donatelli A, Iovane P, Molino A. High energy syngas production by waste tyres steam gasification in a rotary kiln pilot plant. Experimental and numerical investigations[J]. Fuel, 2010,89(10):2721-2728.
[24] Galvagno S, Casu S, Casciaro G, et al. Steam gasification of refuse-derived fuel (RDF): influence of process temperature on yield and product composition[J]. Energy & Fuels, 2006,20(5):2284-2288.
[25] Noma T, Ide K, Yoshikawa J, et al. Development of waste gasification and gas reforming system for municipal solid waste (MSW)[J]. Journal of Material Cycles and Waste Management, 2012,14(3):153-161.
[26] Sasaki T, Sone T, Koyama H, et al. Steam-assisted pyrolysis system for decontamination and volume reduction of radioactive organic waste[J]. Journal of Nuclear Science and Technology, 2009,46(3):232-238.
[27] Sone T, Sasaki T, Yamaguchi H. Reduction of radioactive secondary waste with steam reforming in treatment of waste TBP/dodecane[C]//The 11th International Conference on Environmental Remediation and Radioactive Waste Management. American Society of Mechanical Engineers Digital Collection, 2009:885-889.
[28] Sone T, Nonaka K, Sasaki T, et al. Treatment of simulated waste TBP/n-dodecan and halogenated oils with steam reforming system[R]. Japan Atomic Energy Agency, 2008.
[29] Sone T, Nakagawa A, Koyama H, et al. Long term treatment of waste TBP/n-dodecane with steam reforming system[R]. Japan Atomic Energy Agency, 2009.
[30] Nakagawa A, Sone T, Sasaki T, et al. Treatment technology development of uranium contaminated spent TBP/n-dodecane solvent by steam reforming[R]. JAEA-Technology, 2010.
[31] Takai M, Aoyama M, Nakazawa O, et al. Steam reforming: alternative pyrolytic technology to incineration for volume reduction and stabilization of low-level radioactive organic liquid wastes[J]. Journal of Physics and Chemistry of Solids, 2005,66(2-4):694-696.
[32] Wang J, Xiao B, Liu S, et al. Catalytic steam gasification of pig compost for hydrogen-rich gas production in a fixed bed reactor[J]. BioresourceTechnology, 2013,133:127-133.
[33] Chun Y N, Kim S C, Yoshikawa K. Pyrolysis gasification of dried sewage sludge in a combined screw and rotary kiln gasifier[J]. Applied Energy, 2011,88(4):1105-1112.
[34] Efika C E, Wu C, Williams P T. Syngas production from pyrolysis-catalytic steam reforming of waste biomass in a continuous screw kiln reactor[J]. Journal of Analytical and Applied Pyrolysis, 2012,95:87-94.